If you need to have two separate My Docs Online Login IDs / accounts connected via a Windows Web Folder Network Place you need to set up separate definitions using different URLs to avoid the problem of Windows “remembering” the first Login ID.

You can set up the second ID by pointing it to our other, functionally identical webfolders server.

Presumably you have set the first webfolders account up at https://webfolders.mydocsonline.com, if that is the case try setting up the second account at https://webfolders2.mydocsonline.com.

This will cause Windows to treat the second server as “new” so that it asks for an ID and password.

The resulting Network Place can be named anything you choose, so you can name each one to reflect the ID logged in via that Network Place.